Gibbs free energy: G or ∆G?

One of my objectives in creating a more effective approach to teaching thermodynamics is to bring clarity to some of the confusing terms and concepts embedded in this field. Initially I focused on the concept of heat by pointing out that there is no such thing. I now turn toward free energy. As a veryContinue reading “Gibbs free energy: G or ∆G?”

Riddle me this: what is the physical significance of T∆S in Gibbs’ maximum work equation?

Remember this? Maximum work = -∆Grxn = -(∆Hrxn – T∆Srxn) At some point toward the end of undergraduate thermodynamics, we were taught this equation.  Unfortunately, most of us, myself included, graduated without actually understanding it.  Why?  You already know the answer, just by looking at it.  Because entropy is involved.  While many have a reasonableContinue reading “Riddle me this: what is the physical significance of T∆S in Gibbs’ maximum work equation?”